Acetatoaqua{4,4',6,6'-tetra-tert-butyl-2,2'-[(2-pyridylmethyl)iminodimethylene]diphenolato}manganese(III) ethanol solvate

Chard, E. and Dawe, Louise N. and Kozak, C.M. (2010) Acetatoaqua{4,4',6,6'-tetra-tert-butyl-2,2'-[(2-pyridylmethyl)iminodimethylene]diphenolato}manganese(III) ethanol solvate. Acta Crystallographica Section E, 66 (7). pp. 1-14. ISSN 1600-5368

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Abstract

In the title complex, [Mn(C36H50N2O2)(CH3COO)(H2O)]·CH3CH2OH, the MnIII atom is in an octahedral environment and is coordinated by the tetradentate amine-bis(phenolate) ligand, a monodentate acetate anion and a water molecule. An ethanol solvent molecule is also found in the asymmetric unit. The structure displays O-H...O and C-H...O hydrogen bonding.

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