Ring-opening polymerization of cyclohexene oxide using aluminum amine-phenolate complexes

Kerton, Francesca M. and Plommer, Hart and Reim, Immanuel (2015) Ring-opening polymerization of cyclohexene oxide using aluminum amine-phenolate complexes. Dalton Transactions, 44 (27). pp. 12098-12102. ISSN 1477-9234

[img] [English] PDF (The version available in this research repository is a postprint. It has the same peer-reviewed content as the published version, but lacks publisher layout and branding.) - Accepted Version
Available under License Creative Commons Attribution Non-commercial.

Download (484kB)

Abstract

Remarkably active (down to 0.001% Al) catalysts for ring-opening polymerization of cyclohexene oxide under neat reaction conditions are reported. High molecular weight polymers with uniform dispersity are produced. Kinetic data from NMR studies and MALDI-TOF MS data of the polymers provide some mechanistic insight.

Item Type: Article
URI: http://research.library.mun.ca/id/eprint/13370
Item ID: 13370
Department(s): Science, Faculty of > Chemistry
Date: 11 February 2015
Date Type: Publication
Related URLs:

Actions (login required)

View Item View Item

Downloads

Downloads per month over the past year

View more statistics