Single crystal structural characterization of trichlorotetrapyridylbismuth(III) and its pyridine solvate

Kerton, Francesca M. and Dawe, Louise N. and Murphy, Jennifer N. (2014) Single crystal structural characterization of trichlorotetrapyridylbismuth(III) and its pyridine solvate. Journal of Chemical Crystallography, 44 (2). pp. 108-114. ISSN 1572-8854 (Submitted)

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Abstract

Pentagonal bipyramidal (C5H5N)4BiCl3 and its pyridine solvate are reported. The (C5H5N)4BiCl3 complex exhibits both intra- and intermolecular - stacking, while the pyridine solvate does not, but does contain four formula units in the asymmetric unit. A comparison between the coordination geometry of these solvation isomers and a series of isostructural lanthanide complexes is discussed.

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