The v1 vibrational raman spectra of solid methane

Xiao, Ping (1997) The v1 vibrational raman spectra of solid methane. Masters thesis, Memorial University of Newfoundland.

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Abstract

The v1 vibrational Raman spectra of oriented CH₄ single crystals have been measured in the temperature range from 89.4 K to 21.8 K. The experimental results show that the frequency, width and the depolarization ratio of the spectra change with the temperature and the orientation of the crystals. We think these changes are connected to the following factors: (1) Volume changes; (2) Vibration-rotation (coriolis type) interactions; (3) Probably molecular orientation change in some temperature range.

Item Type: Thesis (Masters)
URI: http://research.library.mun.ca/id/eprint/9387
Item ID: 9387
Additional Information: Bibliography: leaves 91-93
Department(s): Science, Faculty of > Physics and Physical Oceanography
Date: 1997
Date Type: Submission
Library of Congress Subject Heading: Raman spectroscopy; Methane--Spectra

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