A VID-based strategy for the synthesis of armchair aromatic belts

Yao, Tieguang (2009) A VID-based strategy for the synthesis of armchair aromatic belts. Doctoral (PhD) thesis, Memorial University of Newfoundland.

[img] [English] PDF - Accepted Version
Available under License - The author retains copyright ownership and moral rights in this thesis. Neither the thesis nor substantial extracts from it may be printed or otherwise reproduced without the author's permission.

Download (9MB)

Abstract

A molecular belt is considered to be an assembly of atoms that has two continuous, nonintersecting edges and a width that is small in relation to its circumference. Molecular belts having surfaces consisting entirely of a polycyclic aromatic framework are referred to "aromatic belts." -- Aromatic belts have stood as challenging synthetic targets for many years. Several approaches to synthesize aromatic belts have been reported. To date, no aromatic belts has been successfully synthesized rationally by assembling small building blocks. -- Bodwell's group has developed a method, valence isomerization followed by dehydrogenation (VID), which can accomplish the formation of highly nonplanar (and thus strained) pyrene units. -- A strategy for the synthesis of cyclophenacene-type aromatic belts (or armchair SWNCT segments) that relies upon a VID reaction is described, and progress toward achieving this goal is presented.

Item Type: Thesis (Doctoral (PhD))
URI: http://research.library.mun.ca/id/eprint/8656
Item ID: 8656
Additional Information: Includes bibliographical references.
Department(s): Science, Faculty of > Chemistry
Date: 2009
Date Type: Submission
Library of Congress Subject Heading: Aromaticity (Chemistry); Dehydrogenation; Isomerization; Valence fluctuations

Actions (login required)

View Item View Item

Downloads

Downloads per month over the past year

View more statistics