Some chemistry of phenylsulfoxyacetic acid and related compounds

Golding, Peter David (1968) Some chemistry of phenylsulfoxyacetic acid and related compounds. Masters thesis, Memorial University of Newfoundland.

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    Available under License - The author retains copyright ownership and moral rights in this thesis. Neither the thesis nor substantial extracts from it may be printed or otherwise reproduced without the author's permission.
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Abstract

Syntheses of α,α-d₂-chloroacetic acid, α,α-d₂-phenylsulfoxyacetic acid, and α,α-d₂-phenylsulfonylacetic acid are described and the suitability of these acids for conductivity measurements in aqueous (H₂O) media has been investigated. The proton-deuteron exchange reaction at the methylene position of phenylsulfoxyacetic acid has been qualitatively examined and shown to be stereoselective, i.e. the two protons (or deuterons) exchange at different rates. The solvent dependence of the chemical shifts of the methylene protons in phenylsulfoxyacetic acid and some related compounds is discussed.

Item Type: Thesis (Masters)
URI: http://research.library.mun.ca/id/eprint/7132
Item ID: 7132
Additional Information: Bibliography: leaves 108-113. -- Includes errata (p. 119-120). The index at the beginning is actually the table of contents.
Department(s): Science, Faculty of > Chemistry
Date: 1968
Date Type: Submission
Library of Congress Subject Heading: Organic compounds--Synthesis; Phenylsulfoxyacetic acid

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