Kerton, Francesca M. and Dawe, Louise N. and Murphy, Jennifer N. (2014) Single crystal structural characterization of trichlorotetrapyridylbismuth(III) and its pyridine solvate. Journal of Chemical Crystallography, 44 (2). pp. 108-114. ISSN 1572-8854 (Submitted)
PDF (Migrated (PDF/A Conversion) from original format: (application/pdf))
- Published Version
Available under License Creative Commons Attribution Non-commercial.
Pentagonal bipyramidal (C5H5N)4BiCl3 and its pyridine solvate are reported. The (C5H5N)4BiCl3 complex exhibits both intra- and intermolecular - stacking, while the pyridine solvate does not, but does contain four formula units in the asymmetric unit. A comparison between the coordination geometry of these solvation isomers and a series of isostructural lanthanide complexes is discussed.
|Keywords:||solvate, bismuth, pyridine complexes, chloride ligands, π-interactions|
|Department(s):||Science, Faculty of > Chemistry|
Actions (login required)